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CHEM / IGCSE

Organic families, fuels and polymers

Organic compounds are classified by functional groups and homologous series. Alkanes undergo combustion and substitution; alkenes contain a carbon–carbon double bond and undergo addition.

Learning objectives

The big idea

Organic compounds are classified by functional groups and homologous series. Alkanes undergo combustion and substitution; alkenes contain a carbon–carbon double bond and undergo addition.

Alcohols, carboxylic acids and esters connect fuels with chemical synthesis. Addition polymers repeat alkene-derived units, while condensation polymers form links with loss of small molecules. Cracking changes molecular size rather than separating a mixture.

Equations and relationships

CnH2n+2\mathrm C_n\mathrm H_{2n+2}

General formula for acyclic saturated alkanes.

Worked example

What is the molecular formula of propane?

Follow the solution

Use n=3 in CₙH₂ₙ₊₂: hydrogen count is 2×3+2=8.

Investigate and explain

Predict the worked result before calculating. Change one input, record the new result, and explain which assumptions still hold.

Related interactive model. Compare its assumptions with the explanation; it is not a complete syllabus lesson.

Open the interactive investigation

Check your understanding

1. Which feature identifies an alkene?

  1. An OH group
  2. A carbon–carbon double bond
  3. Only single carbon bonds
Check the answer and reasoning

A carbon–carbon double bond

The C=C bond is the alkene functional group.

2. What is the molecular formula of propane?

  1. C₃H₆
  2. C₃H₄
  3. C₃H₈
Check the answer and reasoning

C₃H₈

Use n=3 in CₙH₂ₙ₊₂: hydrogen count is 2×3+2=8.

3. Does fractional distillation itself break hydrocarbon bonds?

  1. No
  2. Yes
  3. Only for large molecules
Check the answer and reasoning

No

Distillation separates by boiling behaviour; cracking breaks covalent bonds.