AeroLab Reading room

CHEM / IGCSE

Electrolysis, metals and redox

Oxidation is electron loss and reduction is electron gain. Electrolysis uses electrical energy to drive decomposition; cations migrate to the negative cathode and anions to the positive anode.

Learning objectives

The big idea

Oxidation is electron loss and reduction is electron gain. Electrolysis uses electrical energy to drive decomposition; cations migrate to the negative cathode and anions to the positive anode.

A reactivity series predicts displacement and extraction methods. Molten and aqueous electrolytes can give different products because water provides competing species; electrode material can also matter.

Equations and relationships

Cu2++2e−→Cu\mathrm{Cu}^{2+}+2e^-\rightarrow\mathrm{Cu}

Reduction at a cathode.

Worked example

How many electrons reduce one Cu²⁺ ion to copper?

Follow the solution

Two electrons balance the +2 charge, producing a neutral atom.

Investigate and explain

Predict the worked result before calculating. Change one input, record the new result, and explain which assumptions still hold.

Use the evidence activity below; no exact PhET model is claimed.

Open the interactive investigation

Check your understanding

1. Which process is oxidation?

  1. Electron loss
  2. Electron gain
  3. Proton gain only
Check the answer and reasoning

Electron loss

Oxidation and reduction occur together through electron transfer.

2. How many electrons reduce one Cu²⁺ ion to copper?

  1. 1
  2. 2
  3. 4
Check the answer and reasoning

2

Two electrons balance the +2 charge, producing a neutral atom.

3. Will a less reactive metal displace a more reactive metal from its salt?

  1. Yes
  2. Always if heated
  3. No
Check the answer and reasoning

No

Displacement requires the added metal to be more reactive under the relevant conditions.