AeroLab Reading room

CHEM / AS level

Equilibria, acids and redox

Equilibrium constants express a composition relationship at fixed temperature. Le Chatelier’s principle predicts shifts qualitatively, while oxidation numbers track redox changes.

Learning objectives

The big idea

Equilibrium constants express a composition relationship at fixed temperature. Le Chatelier’s principle predicts shifts qualitatively, while oxidation numbers track redox changes.

Strong and weak acids differ in the extent of ionisation, not simply concentration. Acid–base and redox titrations use balanced equations to connect accurately measured quantities.

Equations and relationships

Kc = [products]^coefficients / [reactants]^coefficients

Use the equilibrium expression for the specific reaction, omitting pure solids and liquids.

Worked example

For H₂ + I₂ ⇌ 2HI, write Kc.

Follow the solution

Each concentration is raised to its stoichiometric coefficient.

Investigate and explain

Predict the worked result before calculating. Change one input, record the new result, and explain which assumptions still hold.

Related interactive model. Compare its assumptions with the explanation; it is not a complete syllabus lesson.

Open the interactive investigation

Check your understanding

1. Can a weak acid be concentrated?

  1. No
  2. Yes
  3. Only if heated
Check the answer and reasoning

Yes

Weak describes partial ionisation; concentration measures amount per volume.

2. For H₂ + I₂ ⇌ 2HI, write Kc.

  1. [HI]/([H₂]+[I₂])
  2. [H₂][I₂]/[HI]²
  3. [HI]²/([H₂][I₂])
Check the answer and reasoning

[HI]²/([H₂][I₂])

Each concentration is raised to its stoichiometric coefficient.

3. Does increasing pressure shift every gas equilibrium right?

  1. No
  2. Yes
  3. Only with a catalyst
Check the answer and reasoning

No

Pressure favours the side with fewer gas molecules, if the two sides differ.